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5.1.1.Synthesis, Characterization and Structure of Copper(II) complex involving Chloride and Tridentae NNS coordinate Schiff base ligand

grap-astract-CIS2017-v5-n1-Baran

Sujit Baran Kumar*, Ankita Solanki

Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara-390002, India; E. mail. sujit_baran@yahoo.com; sujit.kumar-chem @msubaroda.ac.in.

Received: February 13, 2017; accepted: March 28, 2017

ABSTRACT Mononuclear copper(II) complex [CuLCl2] where L = (2-methylsulfanyl-phenyl)-(phenyl-pyridin-2-yl-methylene)amine, a tridentate NNS donor Schiff base ligand has been synthesized and characterized by microanalysis, IR, UV-Visible spectra and magnetic studies. Crystal structure of the complex has been solved by single crystal X-ray diffraction studies and shows the complex has distorted trigonal bipyramidal geometry.

Key words. Copper(II); NNS donor ligand; five coordinate; IR; structure.

(351.0 KiB, 94 downloads)

http://dx.doi.org/10.21060/cis.2017.511

4.3.2. Recent advances in the chemistry of 1,1’-bis(ortho-carborane)

grap-astract-cis2016-v4-n3-sivaev

Igor B. Sivaev

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Corresponding author e-mail: sivaev@ineos.ac.ru

Received: October 01, 2016; accepted: October 26, 2016

Abstract. The chemistry of 1,1’-bis(ortho-carborane) has rapidly developed in recent years since a convenient method was reported for its synthesis. Here we review the recent progress in this field with main emphasis on the synthesis of 1,1’-bis(carborane)- based heterocycles and transition metal complexes as well as metallacarboranes.

 

(3.4 MiB, 347 downloads)

http://dx.doi.org/10.21060/cis.2016.432

 

Citing articles:

  1. Spokoyny, A., Axtell, J. C., Kirlikovali, K. O., Dziedzic, R. M., Gembicky, M. and Rheingold, A. L. (), Magnesium Reagents Featuring a 1,1′-Bis(o-Carborane) Ligand Platform. Eur. J. Inorg. Chem. doi:10.1002/ejic.201700604

4.3.1 Self-assembly of two New Zinc coordination Polymers Based on N-[(3-Pyridine)-sulfonyl]amino Acid: Structure and Fluorescence

grap-astract-CIS2016-v4-n3-Pei-Luo

Pei Luo1, Shi-Xiong Li1, 2, Yi-Min Jiang1*

1 College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, P.R. China

2College of Environment and Energy, South China University of Technology, Guangzhou, 510006, P. R. China

Address correspondence to Yi-Min Jiang, College of Chemistry and Pharmacy, Guangxi Normal University.

Corresponding author e-mail: 790223684@qq.com

Received: May 13, 2016; accepted: July 11, 2016

Abstract:  Two new zinc coordination polymers based on N-[(3-Pyridine)-sulfonyl]amino acid ligand have been synthesized and characterized by single-crystal X-ray diffraction and elemental analysis. The results show that the 1 is a two-dimensional structure coordination polymer and synthesized under room temperature condition; the 2 is a three-dimensional structure coordination polymer and synthesized under hydrothermal synthesis condition. These two structures are formed by 4,4′-dipyridy and 4,4′-azpy for 1 and 2, respectively. A structural comparison of these two coordination polymers suggests that different reaction temperatures play important role in the construction of resulting architectures of 1 and 2. Fluorescence measurements show that 1 has medium fluorescent emission at 374 nm and 2 has medium fluorescent emission at 438 nm.

(1.9 MiB, 253 downloads)

http://dx.doi.org/10.21060/cis.2016.431

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