5.1.1.Synthesis, Characterization and Structure of Copper(II) complex involving Chloride and Tridentae NNS coordinate Schiff base ligand
Sujit Baran Kumar*, Ankita Solanki
Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara-390002, India; E. mail. firstname.lastname@example.org; sujit.kumar-chem @msubaroda.ac.in.
Received: February 13, 2017; accepted: March 28, 2017
ABSTRACT Mononuclear copper(II) complex [CuLCl2] where L = (2-methylsulfanyl-phenyl)-(phenyl-pyridin-2-yl-methylene)amine, a tridentate NNS donor Schiff base ligand has been synthesized and characterized by microanalysis, IR, UV-Visible spectra and magnetic studies. Crystal structure of the complex has been solved by single crystal X-ray diffraction studies and shows the complex has distorted trigonal bipyramidal geometry.
Key words. Copper(II); NNS donor ligand; five coordinate; IR; structure.